MCrAlY (Nickel-base)

22% Cr, 10% Al, 1% Y, Ni-balance

  • Plasma
  • HVOF

MCrAlY nickel-base — nominally Ni-22Cr-10Al-1Y — is the coating that lets a turbine blade survive the fire inside a combustion chamber. This is the bond coat under yttria-stabilized zirconia (YSZ) thermal-barrier coatings, and it's also the standalone hot-corrosion overlay for industrial gas-turbine blades where no ceramic top coat is specified. Cross-references on the print: Oerlikon Metco Amdry 962, Höganäs AMPERIT 410-series, Metco 461NS.

It works by growing a self-healing α-Al₂O₃ (alumina) scale at temperature. The ~1% yttrium addition is the decisive ingredient — it pegs the alumina to the substrate under thermal cycling, the 'reactive-element effect' that defines the MCrAlY family. Chromium contributes a secondary Cr₂O₃ scale that defeats hot corrosion and sulfidation. NASA Glenn's late-1970s flight-rig work established the two-layer NiCrAlY-plus-YSZ architecture still flying today.

At HTS we apply MCrAlY by HVOF for dense (<2% porosity, ~54 MPa bond) standalone overlays, and by atmospheric plasma spray for TBC bond coats where surface roughness helps the ceramic key in. Service temperature 980-1050°C on the bond coat. Typical thickness 3-10 mils under YSZ, 10-20 mils standalone. This is not a wear coating — for abrasion resistance, pick WC-Co. If you have a turbine blade, vane, or combustor liner that needs to live above 900°C, send us the drawing.

Technical data

Hardness
HVOF typ. 450-490 HV as-sprayed (measured 486 HV in peer-reviewed HVOF study); APS typ. 330-420 HV as-sprayed, rising to ~371 HV after 1100°C diffusion heat treatment. Hardness is a byproduct — this is not a wear coating.
Bond strength
HVOF ~7,800 psi (54 MPa) as-sprayed; APS ~4,900 psi (34 MPa) as-sprayed, rising to ~9,000 psi (62 MPa) after 1100°C diffusion heat treatment. Comfortably clears the 5,000 psi (~34 MPa) bond-coat threshold.
Max service temp
1800°F (980°C) oxidation limit when applied by atmospheric plasma spray; 1920°F (1050°C) by HVOF or controlled-atmosphere plasma per Oerlikon Metco. Thermal-shock rigs have demonstrated YSZ/NiCrAlY systems surviving 1242 cycles at 1200°C and 800h isothermal at 1150°C before spallation.
Max service temp
980°C (APS) / 1050°C (HVOF or LPPS/VPS); TBC system operates hotter at the YSZ surface with the bond coat sitting below the oxidation limit.
As-sprayed porosity
HVOF ~1.5-2% (measured 1.56 vol% in peer-reviewed study); APS ~3-6% as-sprayed, densifying to ~1.6% as the thermally grown oxide (TGO) fills inter-lamellar voids in service. Controlled-atmosphere plasma (LPPS/VPS) hits <1%.
Typical thickness
3-10 mils (75-250 µm) as TBC bond coat under YSZ; 10-20 mils (250-500 µm) as a standalone hot-corrosion overlay on industrial gas turbine blades and vanes. Diffusion heat treatment post-spray is standard for aerospace duty.

Where it earns its keep

  • Forms a protective α-Al₂O₃ scale at temperature that is self-healing — scratches and spallation re-oxidize back to continuous scale
  • Yttrium addition (~1 wt%) dramatically improves alumina scale adherence under thermal cycling — the 'reactive-element effect' that defines the MCrAlY family
  • Chromium contributes a secondary Cr₂O₃ scale that resists hot corrosion and sulfidation in contaminated fuel environments
  • Decades of qualified aerospace flight service under OEM proprietary specs (Pratt & Whitney, GE, Rolls-Royce)
  • HVOF deposition gives dense (<2% porosity), well-adhered (54-62 MPa) bond coats that outperform APS for oxidation resistance
  • Thermodynamically compatible with YSZ top coat — the alumina TGO is the chemically stable interface zirconia grows against

Where it doesn't

  • This is a BOND COAT or standalone hot-corrosion OVERLAY — not a wear coating. Do not specify MCrAlY for abrasion, erosion, or sliding-wear duty; choose WC-Co or chromium-carbide NiCr instead.
  • TBC service life is ultimately limited by TGO growth at the MCrAlY / YSZ interface — oxide scale thickness at spallation is the dominant failure criterion.
  • Diffusion heat treatment (typically 1080-1120°C in vacuum or argon) is standard for aerospace duty: it homogenizes the β-NiAl / γ-Ni phase structure, densifies porosity, and maximizes bond strength.
  • HVOF deposition produces denser, more adherent coatings than APS but with a finer particle-size cut and stricter parameter control; LPPS/VPS is the aerospace gold standard where porosity must be <1%.
  • Proprietary aerospace OEM specifications (PWA, B50, MSRR) usually govern qualification — public AMS numbers alone are rarely sufficient for flight hardware.
  • Service-temperature limit (980-1050°C on the bond coat itself) sets the upper bound; YSZ top coat allows the gas-path surface to run hotter while the metal sits below.

Typical applications

  • Bond coat under YSZ thermal-barrier coating (TBC) on aerospace turbine blades and vanes — the single largest use case
  • Bond coat under YSZ on combustor liners, afterburner components, and nozzle hardware
  • Bond coat under YSZ on land-based industrial gas turbine (IGT) hot-section components
  • Standalone hot-corrosion and oxidation overlay on IGT blades where no ceramic top coat is required (marine, syngas, biomass-fired turbines)
  • Refurbishment and re-coating of overlay-coated turbine parts prior to YSZ re-application
  • Aero-engine combustor liner protection (Ni- and Co-base superalloy substrates such as Superni C-263, Hastelloy X, HS-188)
  • Hot-section hardware in exhaust frames, transition ducts, and static vanes in power-generation turbines

Wear modes addressed

  • High-temperature oxidation (the primary service-life limit)
  • Type I and Type II hot corrosion (Na₂SO₄ / V₂O₅ / alkali-sulfate salt attack, 650-925°C)
  • Sulfidation in fuel-contaminant environments
  • Thermal-cycling fatigue at the bond-coat / TGO / YSZ interface (TGO growth-driven spallation)
  • Inter-diffusion with the substrate (Al depletion into the superalloy over extended service)

Industries

  • Aerospace (turbine blades, vanes, combustors, afterburners)
  • Industrial gas turbine power generation (land-based and marine propulsion)
  • Oil & gas mechanical-drive turbines (pipeline compression, LNG)
  • Defense (engine hot sections for military propulsion)
  • Turbine MRO and overhaul shops (stripping, re-bond-coating, YSZ re-application)

Substrates

  • Nickel-base superalloys (Inconel 718, 738, 792, René N5, CMSX-4, Mar-M 247, Superni C-263)
  • Cobalt-base superalloys (Hastelloy X, HS-188, Mar-M 509)
  • Directionally-solidified and single-crystal turbine-blade alloys
  • Combustor-liner sheet alloys (Haynes 230, 188, HS-188)

Which process, when?

HVOF is the dense, high-bond-strength choice for MCrAlY: ~1.5-2% porosity, 54 MPa as-sprayed bond strength, ~486 HV hardness. Best for standalone overlay duty and for bond coats where oxidation life is the priority. Atmospheric plasma spray (APS) is the workhorse for TBC bond coats under YSZ — higher as-sprayed porosity (3-6%) and lower bond strength (~34 MPa) than HVOF, but the controlled roughness at the bond-coat surface is what the ceramic top coat mechanically keys into. Post-spray diffusion heat treatment at 1080-1120°C recovers APS properties (porosity drops to ~3%, bond strength rises to ~62 MPa, hardness to ~371 HV). Low-pressure (LPPS) / vacuum plasma spray (VPS) is the aerospace gold standard: near-wrought density (<1% porosity), oxide-free splats, best creep and oxidation performance — and the highest cost. Pick HVOF for standalone corrosion overlays and dense bond coats. Pick APS for TBC bond coats where roughness is a feature. Pick LPPS/VPS when a flight-critical hot section needs the cleanest possible deposit.

Sources

Data points on this page draw on the following published references. Nothing here replaces a material-specific review by our process engineers — but it's the working starting point.

Material data on this page is provided as a general reference and can vary by lot, substrate, and application. Contact HTS to confirm the right material and specification for your specific part.

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