400 Series Stainless Steel
0.3% C, 1% Ni, 1% Mn, 12–14% Cr, Fe-balance
- Flame
- Arc
- Plasma
- HVOF
400 Series Stainless Steel is the workhorse coating for the bread-and-butter rebuild jobs — worn pump shafts, scored hydraulic cylinders, grooved line shafts, fatigued turbine blades. Chemistry is simple: 12-14% Cr, 1% Ni, 1% Mn, 0.3% C, iron balance — the martensitic family that includes wrought 420, 410, and 431. The 12% chromium floor handles atmospheric and freshwater corrosion; the 0.3% carbon puts the as-sprayed deposit in the 40-45 HRC band and the quench-hardenable chemistry opens the door to 48-56 HRC after heat treat if the part can take it.
At HTS we apply 400-series most often by twin-wire arc spray — fast deposition on cylindrical work, 1/4"-plus build capability for badly worn shafts, bond strength near 10,000 psi on grit-blasted steel. For smaller precision parts and turbine blade repair we shift to plasma or HVOF with a Diamalloy-1002-class powder, trading throughput for density (<2% porosity), higher hardness (520-560 HV0.3), and smoother finish. Service ceiling is 540°C — above that the martensite over-tempers and a nickel-chrome or MCrAlY stack takes over.
Got a pump shaft scored below tolerance, or a hydraulic cylinder the chrome plater won't quote? Send us the part and the fits — we'll tell you whether 420 is the right rebuild, or whether you're in tungsten-carbide territory.
Technical data
- Hardness
- HVOF deposits 520-560 HV0.3 (Diamalloy 1002, ~type 420); APS deposits 271-536 HV0.3 depending on powder cut; arc-sprayed wire typically 350-450 HV as-sprayed
- Hardness (HRC)
- 40-45 HRC as-sprayed (twin-wire arc, PMET 720-class wire); heat-treatable to 48-56 HRC after quench-and-temper (wrought 420 reference); HVOF Diamalloy 1002 equivalent reaches HR15N 84
- Bond strength
- Twin-wire arc approaches 10,000 psi (~69 MPa) on grit-blasted carbon steel; HVOF exceeds 11,600 psi (80 MPa); flame-spray wire/powder typically 5,000-8,000 psi (35-55 MPa); 410SS reference coating coupons measured 259-349 MPa in-plane strength
- Max service temp
- ≤1000°F (540°C) continuous per Oerlikon Metco martensitic SS datasheet DSMTS-0080 — above this the matrix over-tempers and hardness drops
- Max service temp
- ≤540°C continuous service; short excursions tolerated but hardness loss is the limiting factor, not oxidation
- As-sprayed porosity
- HVOF <2% (best-case Diamalloy 1002 coatings <0.3% with optimized twin-arc); APS 1.5-5%; twin-wire arc 3-8%; combustion flame 4-10% — porosity accepts oil and sealers, which is why arc-sprayed 420 holds lubrication on journal surfaces
- Typical thickness
- 5-60 mils production range per HTS arc-spray envelope (0.005"-0.250"); twin-wire arc builds 1/4"+ for dimensional restoration; flame-spray wire practical to 80-100 mils; HVOF 5-20 mils for precision wear surfaces
- Density
- ~7.70 (matches wrought 420 reference)
Where it earns its keep
- Hits the 40-50 HRC hardness band as-sprayed — hard enough to live against journal bearings, soft enough to grind or turn without exotic tooling
- Handles corrosion AND wear in the same deposit — the 12% Cr floor gives mild atmospheric and aqueous resistance where carbon-steel weld build-up rusts
- Thick build capability — twin-wire arc routinely deposits 1/4" or more in a single setup, restoring badly worn shafts and cylinders that chrome plating can't practically fix
- Strong chrome-plate alternative — no hex-chrome waste stream, no rinse tanks, no long-cycle plating bath; applied in hours rather than days
- Grindable to bearing-fit finishes (16 Ra and below) with standard carbide tooling at low speed — no diamond wheels required the way WC-Co demands
- Fast, economical application on large cylindrical work — twin-wire arc is the production workhorse for 20-foot shafts and 100-inch-diameter rolls
Where it doesn't
- 540°C service ceiling — above 1000°F the martensitic matrix over-tempers and hardness falls; specify NiCrAlY or MCrAlY bond-coat-and-topcoat stacks for hot-section duty
- Corrosion-resistant but NOT corrosion-proof — 12% Cr handles atmosphere and fresh water, NOT chlorides, strong acids, or sour H2S service (pick 316L, Hastelloy C-276, or Inconel 625 for those)
- Arc-spray deposits run 3-8% open porosity — sealers (epoxy or phenolic) are recommended on hydraulic cylinder bores and pump wear surfaces exposed to pressurized fluid
- Oxide stringers in twin-wire arc deposits reduce corrosion resistance vs wrought 420 — for corrosion-first duty step up to HVOF or sealed HVAF deposits
- Hardness band sits below tungsten-carbide territory — if the duty is hard-particle abrasion or gouging at 60+ HRC equivalent, step up to WC-CoCr or Stellite 6/12
- Post-spray heat treatment is possible but rarely done on sprayed deposits — wrought 420 hits 48-56 HRC after quench-and-temper; sprayed 420 is usually accepted in its as-sprayed 40-45 HRC state
Typical applications
- Shaft build-up and dimensional restoration on worn pump shafts, motor shafts, and line shafts where corrosion and wear both matter
- Hydraulic cylinder rods and hydraulic rams — chrome-plate alternative with similar hardness and better build thickness
- Steam and low-pressure turbine blades — droplet-erosion protection and repair on stages that run cool enough (<540°C) to keep the martensitic matrix
- Crankshaft journals, bearing journals, and wear-ring mating surfaces on stationary machinery
- Cylinder liners, pump plungers, and piston rods in reciprocating machinery
- Valve stems, seat surfaces, and mechanical seal faces where soft-dense 316L is too soft and a carbide is overkill
- Press-fit bearing seats, machine bedways, and feed-roll surfaces resisting fretting
- Wire-drawing capstans, pulleys, and sheaves where hard-surface wear meets mild corrosion
- Salvage and rebuild of mis-machined or worn grindable steel parts before re-dimensioning
- Hydroelectric valve trim, exhaust fans, and hydro-turbine components for mild-duty particle erosion
Wear modes addressed
- Adhesive wear and galling on shaft journals and sliding fits
- Abrasive wear from hard-particle contact at low-to-moderate temperature
- Fretting wear at press-fits, bearing seats, and vibrating mating surfaces
- Water-droplet and low-angle particle erosion on turbine blades and valve trim
- Mild aqueous and atmospheric corrosion (the 12% Cr floor is the corrosion-resistance argument)
- Cavitation on pump and hydro-turbine components (secondary — tungsten carbide does this better)
Industries
- Pulp and paper (press rolls, dryer rolls, pump shafts, valve trim)
- Hydropower and water / wastewater (turbine blades, valve trim, pump components)
- Steel and aluminum processing (work rolls, levelers, tension rolls, run-out table parts)
- Oil and gas (pump shafts, mud pump liners, valve bodies in mild-sour service)
- Power generation (low-pressure turbine blade stages, feedwater pump shafts)
- General manufacturing and machine rebuild (shafts, crankshafts, hydraulic rods, gearbox components)
- Food processing and pharmaceutical (corrosion-resistant wear surfaces on mixers and conveyors)
- Marine and offshore (deck machinery shafts, winch drums, mild-seawater service)
Substrates
- Carbon and low-alloy steels (1045, 4140, 4340, A36) — the primary arc-spray substrate for shaft and cylinder work
- Cast irons (gray, ductile) on engine and pump components
- Austenitic stainless steels (304, 316, 316L) where a harder wear face is needed over a corrosion-resistant core
- Tool steels and bearing steels (52100, D2) for localized repair
- Existing 420 / 410 / 416 martensitic stainless shafts returning to OEM diameter after wear
Which process, when?
Twin-wire arc spray (TWAS) is the production workhorse for 400-series stainless on shafts, rolls, and cylinders. Fast deposition rate, 3-8% porosity, bond strength approaching 10,000 psi, and 1/4"+ build capability make it the right call for dimensional restoration work — pump shafts, crankshafts, hydraulic rods, paper-mill rolls. Combustion flame-spray wire (oxy-fuel wire pistol) covers the same duty at slightly tighter porosity (4-10%) and lower deposition rate; useful on smaller parts and field repairs where a pistol-and-bottles setup is easier to rig than a full arc-spray cell. Atmospheric plasma spray (APS) with Metco 42C or Diamalloy 1002 powder delivers denser deposits (1.5-5% porosity) with higher hardness (HR15N 65-79) — picked when a harder, denser 420-class surface is needed on smaller precision parts and turbine blade repair. HVOF (Diamalloy 1002) is the high-end answer: <2% porosity, >11,600 psi bond, 520-560 HV0.3 hardness, smoother and less oxidized than any of the above. Pick arc-spray for throughput on big cylindrical work, flame for small parts and mobile repair, plasma for hardness-plus-density on precision jobs, HVOF when porosity is the failure mode.
Sources
Data points on this page draw on the following published references. Nothing here replaces a material-specific review by our process engineers — but it's the working starting point.
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Oerlikon Metco DSMTS-0080.7 — Martensitic Stainless Steel Powders (Metco 42C, Diamalloy 1002)
“Diamalloy 1002 is a martensitic chromium stainless steel powder similar to type 420 SS; APS deposits HR15N 65 / HV0.3 271; HVOF deposits HR15N 84 / HV0.3 520-560; maximum service temperature ≤540°C (1000°F); recommended spray processes APS and HVOF.”
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Oerlikon myMetco — Metco 42C Martensitic Stainless Steel Thermal Spray Powder
“Metco 42C is a martensitic, high-chromium stainless steel powder similar to type 431 stainless; produces coatings combining fair wear resistance and impact strength with the best corrosion resistance of any martensitic stainless steel; service ≤540°C, applied via APS or CPS.”
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Polymet PMET 720 — Type 420 Stainless Steel Thermal Spray Wire Datasheet
“Nominal composition 13.0% Cr, 1.0% Si, 1.0% Mn, 0.3% C, Fe balance; Rockwell C 40-45 hardness; forms dense, well-bonded coating with excellent wear resistance and good corrosion resistance; used for machine-element repair, dimensional restoration, and wear-resistant applications.”
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A&A Coatings — Metallized 410 Stainless Steel Wire Specifications
“Composition 0.35% C, 13% Cr, 0.5% Ni, 0.35% Mn, 0.5% Si, Fe balance; macrohardness Rc 33 as-sprayed; coating tensile strength 40,000 psi; suits journal surfaces, cylinder liners, pistons, valve stems, pump plungers, hydraulic rams, crankshaft bearings.”
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Western Machine Works — 420 Stainless Steel Twin-Wire Arc Coating Services
“Twin-wire arc metal spray process for component restoration using 420 stainless steel; performs well under compression and resists corrosion and erosion; chromium content 13% with 0.35% carbon; suited for shafts, cylinder liners, crankshaft bearings, and most moving parts.”
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Höganäs AMPERIT Thermal Spray Powders — Martensitic Stainless Steel Family
“Höganäs AMPERIT product family includes gas- and water-atomized iron-based martensitic stainless-steel powders for HVOF, APS, and cold-spray, designed for wear protection and dimensional restoration on machine components.”
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HTS Coatings — Arc Spray Process and Materials
“Arc spray materials include Monel, Inconel, stainless steel, Hastelloy, zinc, aluminum, tin, and copper; coating thickness range 0.005" to 0.250"; recommended for shaft enhancement or repair, feed-roll enhancement or repair, and no-slip coatings.”
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Materials Science Forum — Physical and Mechanical Properties of Twin-Wire Arc and Flame-Spray Coatings on Carbon Steel
“Twin-wire arc 420 stainless coatings on carbon steel substrate show bond strength approaching 10,000 psi; optimized twin-arc process achieves less than 0.3% porosity; average coating strength 259-349 MPa depending on spray conditions.”
Material data on this page is provided as a general reference and can vary by lot, substrate, and application. Contact HTS to confirm the right material and specification for your specific part.
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